Titanium perchlorate

Titanium perchlorate
Identifiers
CAS Number	60580-20-3; 13498-15-2;
3D model (JSmol)	Interactive image;
PubChem CID	14795113;
	InChI InChI=1S/4ClHO4.Ti/c42-1(3,4)5;/h4(H,2,3,4,5);/q;;;;+4/p-4 Key: SOCDLWOJPVKBHF-UHFFFAOYSA-J;
	SMILES [Ti](O[Cl](=O)(=O)=O)(O[Cl](=O)(=O)=O)(O[Cl](=O)(=O)=O)O[Cl](=O)(=O)=O;
Properties
Chemical formula	Ti(ClO4)4
Molar mass	445.65 g·mol−1
Appearance	white crystals, ; deliquescent
Density	2.49 g/cm3 (anhydrous)
Melting point	85 °C (185 °F; 358 K) (anhydrous) slight decomposition
Boiling point	decomposition
Solubility in water	high
Related compounds
Other anions	Titanium nitrate
Other cations	Zirconium perchlorate; Hafnium perchlorate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Titanium perchlorate is a molecular compound of titanium and perchlorate groups with formula Ti(ClO₄)₄. Anhydrous titanium perchlorate decomposes explosively at 130 °C and melts at 85 °C with a slight decomposition. It can sublime in a vacuum as low as 70 °C, and can form vapour at up to 120°. Titanium perchlorate is quite volatile. It has density 2.35. It decomposes to TiO₂, ClO₂ and dioxygen O₂ Also TiO(ClO₄)₂ is formed during decomposition.^[2]

Ti(ClO₄)₄ → TiO₂ + 4ClO₂ + 3O₂ ΔH = +6 kcal/mol (25 kJ/mol).^[2]

^ Cite error: The named reference foura was invoked but never defined (see the help page).
^ ^a ^b Babaeva, V. P.; Rosolovskii, V. (1974). "Volatile titanium perchlorate". Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 23 (11): 2330–2334. doi:10.1007/BF00922105. ISSN 0568-5230.

[foura-1] Cite error: The named reference foura was invoked but never defined (see the help page).

[Babaeva1974-2] Babaeva, V. P.; Rosolovskii, V. (1974). "Volatile titanium perchlorate". Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 23 (11): 2330–2334. doi:10.1007/BF00922105. ISSN 0568-5230.

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[2]

Identifiers

CAS Number	60580-20-3^[1] 13498-15-2
3D model (JSmol)	Interactive image
PubChem CID	14795113
InChI InChI=1S/4ClHO4.Ti/c42-1(3,4)5;/h4(H,2,3,4,5);/q;;;;+4/p-4 Key: SOCDLWOJPVKBHF-UHFFFAOYSA-J
SMILES [Ti](O[Cl](=O)(=O)=O)(O[Cl](=O)(=O)=O)(O[Cl](=O)(=O)=O)O[Cl](=O)(=O)=O
Properties
Chemical formula	Ti(ClO₄)₄
Molar mass	445.65 g·mol⁻¹
Appearance	white crystals, deliquescent
Density	2.49 g/cm³ (anhydrous)
Melting point	85 °C (185 °F; 358 K) (anhydrous) slight decomposition
Boiling point	decomposition
Solubility in water	high
Related compounds
Other anions	Titanium nitrate
Other cations	Zirconium perchlorate Hafnium perchlorate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Titanium perchlorate

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