Chromium(II) acetate

Chromium(II) acetate
Names
IUPAC name
Chromium(II) acetate hydrate
Other names
chromous acetate,
chromium diacetate,
chromium(II) ethanoate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.224.848 Edit this at Wikidata
RTECS number
  • AG3000000
UNII
  • InChI=1S/2C2H4O2.Cr/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2 checkY
    Key: LRCIYVMVWAMTKX-UHFFFAOYSA-L checkY
  • InChI=1/2C2H4O2.Cr/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
    Key: LRCIYVMVWAMTKX-NUQVWONBAT
  • [Cr+2]1234([OH2])#[Cr+2]([OH2])(O[C-](C)O1)(O[C-](C)O2)(O(C)[C-]O3)O(C)[C-]O4
Properties
C8H16Cr2O10
Molar mass 376.198 g·mol−1
Appearance brick-red solid
Density 1.79 g/cm3
Melting point dehydrates
soluble in hot water, MeOH
-5104.0·10−6 cm3/mol
Structure
monoclinic
octahedral
counting the Cr–Cr bond
0 D
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
could react exothermically in air
Related compounds
Related compounds
Rh2(OAc)4(H2O)2
Cu2(OAc)4(H2O)2, molybdenum(II) acetate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chromium(II) acetate hydrate, also known as chromous acetate, is the coordination compound with the formula Cr2(CH3CO2)4(H2O)2. This formula is commonly abbreviated Cr2(OAc)4(H2O)2. This red-coloured compound features a quadruple bond. The preparation of chromous acetate once was a standard test of the synthetic skills of students due to its sensitivity to air and the dramatic colour changes that accompany its oxidation. It exists as the dihydrate and the anhydrous forms.

Cr2(OAc)4(H2O)2 is a reddish diamagnetic powder, although diamond-shaped tabular crystals can be grown. Consistent with the fact that it is nonionic, Cr2(OAc)4(H2O)2 exhibits poor solubility in water and methanol.

Chromium(II) acetate (aqueous solution)

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