Ethylene glycol

Ethylene glycol
Wireframe model of ethylene glycol
Spacefill model of ethylene glycol
Spacefill model of ethylene glycol
Ball and stick model of ethylene glycol
Ball and stick model of ethylene glycol
Sample of ethylene glycol
Names
IUPAC names
Ethylene glycol[1]
Ethane-1,2-diol[2]
Preferred IUPAC name
Ethane-1,2-diol[3]
Other names
  • Ethylene glycol
  • 1,2-Ethanediol
  • Ethylene alcohol
  • Hypodicarbonous acid
  • Monoethylene glycol
  • 1,2-Dihydroxyethane
  • Glycol solvent
Identifiers
3D model (JSmol)
3DMet
Abbreviations MEG
505945
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.003.159 Edit this at Wikidata
EC Number
  • 203-473-3
943
KEGG
MeSH Ethylene+glycol
RTECS number
  • KW2975000
UNII
UN number 3082
  • InChI=1S/C2H6O2/c3-1-2-4/h3-4H,1-2H2 checkY
    Key: LYCAIKOWRPUZTN-UHFFFAOYSA-N checkY
  • InChI=1/C2H6O2/c3-1-2-4/h3-4H,1-2H2
    Key: LYCAIKOWRPUZTN-UHFFFAOYAD
  • OCCO
Properties
C2H6O2
Molar mass 62.068 g·mol−1
Appearance Clear, colorless liquid
Odor Odorless[4]
Density 1.1132 g/cm3 (0.04022 lb/cu in)
Melting point −12.9 °C (8.8 °F; 260.2 K)
Boiling point 197.3 °C (387.1 °F; 470.4 K)
Miscible
Solubility Soluble in alcohols, ethyl acetate, THF, and dioxane. Miscible with DCM and slightly miscible with diethyl ether. Not miscible with toluene or hexanes.
log P -1.69[5]
Vapor pressure 0.06 mmHg (20 °C)[4]
Viscosity 1.61×10−2 Pa·s[6]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Harmful, produces poisonous oxalic acid when ingested, flammable
GHS labelling:
GHS07: Exclamation markGHS08: Health hazard
Warning
H302, H373
P260, P264, P270, P301+P312, P302, P314, P330, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
1
0
Flash point 111 °C (232 °F; 384 K) closed cup
410 °C (770 °F; 683 K)
Explosive limits 3.2–15.2%[4]
NIOSH (US health exposure limits):
PEL (Permissible)
None[4]
REL (Recommended)
None established[4]
IDLH (Immediate danger)
None[4]
Safety data sheet (SDS) External SDS 1

External SDS 2

Related compounds
Related diols
Supplementary data page
Ethylene glycol (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Ethylene glycol (IUPAC name: ethane-1,2-diol) is an organic compound (a vicinal diol[7]) with the formula (CH2OH)2. It is mainly used for two purposes, as a raw material in the manufacture of polyester fibers and for antifreeze formulations. It is an odorless, colorless, flammable, viscous liquid. It has a sweet taste, but is toxic in high concentrations. This molecule has been observed in outer space.[8]

  1. ^ "Ethylene glycol (CHEBI:30742)".
  2. ^ "Ethylene glycol (CHEBI:30742)".
  3. ^ International Union of Pure and Applied Chemistry (2014). Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013. The Royal Society of Chemistry. p. 690. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.
  4. ^ a b c d e f NIOSH Pocket Guide to Chemical Hazards. "#0272". National Institute for Occupational Safety and Health (NIOSH).
  5. ^ "Ethylene glycol". www.chemsrc.com.
  6. ^ Elert, Glenn. "Viscosity". The Physics Hypertextbook. Retrieved 2007-10-02.
  7. ^ "3.8: 3.8 Alcohols - Classification and Nomenclature". Chemistry LibreTexts. 2018-10-13. Retrieved 2022-04-21.
  8. ^ J. M. Hollis; F. J. Lovas; P. R. Jewell; L. H. Coudert (2002-05-20). "Interstellar Antifreeze: Ethylene Glycol". The Astrophysical Journal. 571 (1): L59–L62. Bibcode:2002ApJ...571L..59H. doi:10.1086/341148. S2CID 56198291.

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