Rutherfordium

Rutherfordium, 104Rf
Rutherfordium
Pronunciation/ˌrʌðərˈfɔːrdiəm/ (RUDH-ər-FOR-dee-əm)
Mass number[267]
Rutherfordium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Hf

Rf

(Upo)
lawrenciumrutherfordiumdubnium
Atomic number (Z)104
Groupgroup 4
Periodperiod 7
Block  d-block
Electron configuration[Rn] 5f14 6d2 7s2[1][2]
Electrons per shell2, 8, 18, 32, 32, 10, 2
Physical properties
Phase at STPsolid (predicted)[1][2]
Melting point2400 K ​(2100 °C, ​3800 °F) (predicted)[1][2]
Boiling point5800 K ​(5500 °C, ​9900 °F) (predicted)[1][2]
Density (near r.t.)17 g/cm3 (predicted)[3][4]
Atomic properties
Oxidation states(+2), (+3), +4[1][2][5] (parenthesized: prediction)
Ionization energies
  • 1st: 580 kJ/mol
  • 2nd: 1390 kJ/mol
  • 3rd: 2300 kJ/mol
  • (more) (all but first estimated)[2]
Atomic radiusempirical: 150 pm (estimated)[2]
Covalent radius157 pm (estimated)[1]
Other properties
Natural occurrencesynthetic
Crystal structurehexagonal close-packed (hcp)
Hexagonal close-packed crystal structure for rutherfordium

(predicted)[6]
CAS Number53850-36-5
History
Namingafter Ernest Rutherford
DiscoveryJoint Institute for Nuclear Research and Lawrence Berkeley National Laboratory (1969)
Isotopes of rutherfordium
Main isotopes[7] Decay
abun­dance half-life (t1/2) mode pro­duct
261Rf synth 2.1 s SF82%
α18% 257No
263Rf synth 15 min[8] SF<100%?
Preview warning: Infobox Rf isotopes: Decay mode percentage not recognised "perc1=<100%?" cat#%
α~30%?
Preview warning: Infobox Rf isotopes: Decay mode percentage not recognised "perc2=~30%?" cat#%
259No
265Rf synth 1.1 min[9] SF
267Rf synth 48 min[10] SF
 Category: Rutherfordium
| references

Rutherfordium is a synthetic chemical element; it has symbol Rf and atomic number 104. It is named after physicist Ernest Rutherford. As a synthetic element, it is not found in nature and can only be made in a particle accelerator. It is radioactive; the most stable known isotope, 267Rf, has a half-life of about 48 minutes.

In the periodic table, it is a d-block element and the second of the fourth-row transition elements. It is in period 7 and is a group 4 element. Chemistry experiments have confirmed that rutherfordium behaves as the heavier homolog to hafnium in group 4. The chemical properties of rutherfordium are characterized only partly. They compare well with the other group 4 elements, even though some calculations had indicated that the element might show significantly different properties due to relativistic effects.

In the 1960s, small amounts of rutherfordium were produced at Joint Institute for Nuclear Research in the Soviet Union and at Lawrence Berkeley National Laboratory in California.[11] Priority of discovery and hence the name of the element was disputed between Soviet and American scientists, and it was not until 1997 that the International Union of Pure and Applied Chemistry (IUPAC) established rutherfordium as the official name of the element.

  1. ^ a b c d e f "Rutherfordium". Royal Chemical Society. Retrieved 2019-09-21.
  2. ^ a b c d e f g Hoffman, Darleane C.; Lee, Diana M.; Pershina, Valeria (2006). "Transactinides and the future elements". In Morss; Edelstein, Norman M.; Fuger, Jean (eds.). The Chemistry of the Actinide and Transactinide Elements (3rd ed.). Dordrecht, The Netherlands: Springer Science+Business Media. ISBN 978-1-4020-3555-5.
  3. ^ Gyanchandani, Jyoti; Sikka, S. K. (10 May 2011). "Physical properties of the 6 d -series elements from density functional theory: Close similarity to lighter transition metals". Physical Review B. 83 (17): 172101. Bibcode:2011PhRvB..83q2101G. doi:10.1103/PhysRevB.83.172101.
  4. ^ Kratz; Lieser (2013). Nuclear and Radiochemistry: Fundamentals and Applications (3rd ed.). p. 631.
  5. ^ Fricke, Burkhard (1975). "Superheavy elements: a prediction of their chemical and physical properties". Recent Impact of Physics on Inorganic Chemistry. Structure and Bonding. 21: 89–144. doi:10.1007/BFb0116498. ISBN 978-3-540-07109-9. Retrieved 4 October 2013.
  6. ^ Östlin, A.; Vitos, L. (2011). "First-principles calculation of the structural stability of 6d transition metals". Physical Review B. 84 (11): 113104. Bibcode:2011PhRvB..84k3104O. doi:10.1103/PhysRevB.84.113104.
  7. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  8. ^ Sonzogni, Alejandro. "Interactive Chart of Nuclides". National Nuclear Data Center: Brookhaven National Laboratory. Retrieved 2008-06-06.
  9. ^ Utyonkov, V. K.; Brewer, N. T.; Oganessian, Yu. Ts.; Rykaczewski, K. P.; Abdullin, F. Sh.; Dimitriev, S. N.; Grzywacz, R. K.; Itkis, M. G.; Miernik, K.; Polyakov, A. N.; Roberto, J. B.; Sagaidak, R. N.; Shirokovsky, I. V.; Shumeiko, M. V.; Tsyganov, Yu. S.; Voinov, A. A.; Subbotin, V. G.; Sukhov, A. M.; Karpov, A. V.; Popeko, A. G.; Sabel'nikov, A. V.; Svirikhin, A. I.; Vostokin, G. K.; Hamilton, J. H.; Kovrinzhykh, N. D.; Schlattauer, L.; Stoyer, M. A.; Gan, Z.; Huang, W. X.; Ma, L. (30 January 2018). "Neutron-deficient superheavy nuclei obtained in the 240Pu+48Ca reaction". Physical Review C. 97 (14320): 014320. Bibcode:2018PhRvC..97a4320U. doi:10.1103/PhysRevC.97.014320.
  10. ^ Oganessian, Yu. Ts.; Utyonkov, V. K.; Ibadullayev, D.; et al. (2022). "Investigation of 48Ca-induced reactions with 242Pu and 238U targets at the JINR Superheavy Element Factory". Physical Review C. 106 (24612): 024612. Bibcode:2022PhRvC.106b4612O. doi:10.1103/PhysRevC.106.024612. S2CID 251759318.
  11. ^ "Rutherfordium - Element information, properties and uses | Periodic Table". www.rsc.org. Retrieved 2016-12-09.

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