Trimethylolpropane phosphite

Trimethylolpropane phosphite
Names
Preferred IUPAC name
4-Ethyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane
Other names
EtCage; Ethyl bicyclic phosphite; Trishydroxymethylpropane bicyclic phosphite
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.011.385 Edit this at Wikidata
EC Number
  • 212-523-3
UNII
  • InChI=1S/C6H11O3P/c1-2-6-3-7-10(8-4-6)9-5-6/h2-5H2,1H3 ☒N
    Key: QRUSNTDXJQBKBI-UHFFFAOYSA-N ☒N
  • InChI=1/C6H11O3P/c1-2-6-3-7-10(8-4-6)9-5-6/h2-5H2,1H3
    Key: QRUSNTDXJQBKBI-UHFFFAOYAD
  • O1P2OCC(CC)(C1)CO2
Properties
C6H11O3P
Molar mass 162.125 g·mol−1
Appearance white waxy solid
Melting point 56 °C (133 °F; 329 K)
organic solvents
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Trimethylolpropane phosphite, C2H5C(CH2O)3P, is a phosphite ester used as a ligand in organometallic chemistry. Trimethylolpropane phosphite is sometimes abbreviated to EtCage. It is a white solid that is soluble in organic solvents. It is also highly toxic.[1]

  1. ^ Ende, Christopher; Parker, Kathlyn (2014). "4-Ethyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane". e-EROS Encyclopedia of Reagents for Organic Synthesis. pp. 1–3. doi:10.1002/047084289X.rn01781. ISBN 9780470842898.

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